We develop methods to probe the excitation spectrum of topological phases of matter in two spatial dimensions. Applying these to the Fibonacci string nets perturbed away from exact solvability, we analyze a topological phase transition driven by the condensation of non-Abelian anyons. Our numerical results illustrate how such phase transitions involve the spontaneous breaking of a topological symmetry, generalizing the traditional Landau paradigm. The main technical tool is the characterization of the ground states using tensor networks and the topological properties using matrix-product-operator symmetries. The topological phase transition manifests itself by symmetry breaking in the entanglement degrees of freedom of the quantum transfer matrix.
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